Obtaining nanodisperse powders of neodymium-activated yttrium aluminum garnet by self-propagating high-temperature synthesis method

Nanosized slightly agglomerated powders of neodymium-activated yttrium aluminum garnet (YAG:Nd) were obtained by a self-propagating high-temperature synthesis method. An increase in content of reducing substituents in metal-organic complexes as compared to oxidizing substituents leads to an increase in average size of the forming grains from 23 to 70 nm; thereupon, a decrease in powder agglomeration degree is observed. Firing of x-ray amorphous powders results in formation of polycrystalline YAG:Nd without forming intermediate phases.     

New Type of the Electron Emission Induced by the Electric Field

A new type of the electron emission induced by a pulsed electric field with a strength of about 105 V/cm applied to the cathode made of graphene-like structures has been found. Pulsed currents of up to several hundred amperes have been obtained in a range of 1–5 ns. It has been found that the length of the current pulse depends on the strength of the electric field and decreases with an increase in this strength at a constant length of the electric field pulse; the electron emission time as well as the maximum emission current are determined by the value of the bound charge in the region of the cathode surface; and the process relaxation time after extraction of the emission current exceeds 300 ns.     

Over-phase control of inverter multiphase AC linear drives

The over-phase control method of inverter multiphase (i.e. having number of phases more than four) AC linear drives is developed by the authors of this paper. Its application allows to improve considerably a number of the drive technical-and-economic characteristics (speed of response, reliability, mass-and-overall dimensions, etc.). This control method can be used not only in the field of electrical AC drives, but also in the systems for electromagnetic stirring of molten metals. In these systems the application of one of versions of the over-phase-control for multiphase inverter-fed linear stators allows to increase the intensity of electromagnetic stirring of molten metals by providing with continuous change of the quantity, space location, and configuration of the vortex areas in the metal mass during the process of the above-mentioned stirring.     

Pulsed electromagnetic attraction of sheet metals – Fundamentals and perspective applications

The paper is dedicated to the study of pulsed electromagnetic attraction processes which can deform ferromagnetic sheet metal materials such as low carbon steels using low frequency discharges. The analytical model based upon the solution of Maxwell equations explains that magnetic forces are prevailing over the Lorentz forces for low frequency discharges. For electromagnetic forming (EMF) processes employing ferromagnetic sheet metal blanks of low electrical conductivity with relatively slow electric discharges, the magnetic forces should be taken into account in order to achieve a correct representation of electromagnetic forces applied to the blank. An engineering estimate on the size of magneto-static forces and Lorentz-forces is the outcome of the analytical work. In addition to analytical work and validation of the proposed engineering estimate of attracting forces, a single turn coil is introduced which is more robust than previous designs with multiple frequencies and interrupted discharges. The simplified setup only requires a rather slow single frequency low voltage electric discharge which allows for using cheaper and longer life capacitors, substantially reduces the safety implications and also extends the life of the coil insulation.     

Determination of Activity Coefficients of Semi-Volatile Organic Aerosols Using the Integrated Volume Method

We demonstrate the use of the Integrated Volume Method (IVM) to estimate activity coefficients of semi-volatile organic compounds pertinent to ambient/atmospheric aerosols in binary mixtures. We generate binary solution aerosols with different mole fractions of individual components; for each mixture, we measure total change in aerosol volume upon heating from 25 ^○ C to 35 ^○ C, with the aerosols being at equilibrium in both states. The change in aerosol volume, or in other words, the partitioning between the particle phase and the gas phase, is used to determine activity coefficients of the compounds as a function of their mole fraction in the mixture. We demonstrate this method using the following four model systems. System 1: adipic acid–pimelic acid, which illustrates polar organic–polar organic interactions. Non-ideal behavior was observed with activity coefficients around three at infinite dilution. System 2: adipic acid–dioctyl sebacate, which illustrates polar organic–non-polar organic interactions. The compounds in this experiment did not form a solution. System 3: adipic acid–ammonium sulfate, which illustrates polar organic–inorganic interactions. The compounds in this experiment did not form a solution. System 4: adipic acid–ambient extracts, which illustrates the potential use of the method to study partitioning behavior of individual components in a complex matrix approximating that of real ambient aerosol. The measured activity coefficients of adipic acid were less than unity for the tested range of mixing ratios, indicating suppression of volatility of this compound in ambient organic matrix.     

Growth and characterisation of BNC nanostructures

BNC nanostructures were produced by the resistive heating of graphite and boric acid powder in a high isostatic pressure apparatus at a temperature of ∼1650 °C, with a nitrogen pressure of 12 MPa. The resultant nanostructures were examined using transmission electron microscopy, electron energy-loss spectroscopy and X-ray photoelectron spectroscopy. The growth mechanisms of the nanostructures are discussed.     

Adsorption of methyl mercaptan on activated carbons

Activated carbons of different origins were studied as methyl mercaptan adsorbents in wet, dry, and oxidizing conditions. The materials were characterized using adsorption of nitrogen, Boehm titration, and thermal analysis. Investigation was focused on the feasibility of the removal of methyl mercaptan on activated carbons and on the role of surface chemistry and porosity in the adsorption/oxidation processes. The results showed relatively high capacities of carbons for removal of CH3SH. The amount adsorbed depends on the surface features. Methyl mercaptan, in general, is oxidized to disulfides, which, depending on the chemistry of the carbon surface, can be converted to sulfonic acid due to the presence of water and active radicals.     

Supervised learning technique for a mobile robot controller in a visual line tracking task

This article deals with the development of learning methods for an intelligent control system for an autonomous mobile robot. On the basis of visual servoing, an approach to learning the skill of tracking colored guidelines is proposed. This approach utilizes a robust and adaptive image processing method to acquire features of the colored guidelines and convert them into the controller input. The supervised learning procedure and the neural network controller are discussed. The method of obtaining the learning data and training the neural network are described. Experimental results are presented at the end of the article. This work was presented, in part, at the Sixth International Symposium on Artificial Life and Robotics, Tokyo, Japan, January 15–17, 2001